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Continue Valency of all 118 elements The periodic table, shown on the left, can tell us a great deal about the valency of elements. Elements are placed in groups (columns) in the periodic table according to the number of valence electrons, so naturally the position of the element in the periodic table should give us an idea of its valency. All elements in group 1 have 1 valence electron so they have a valency of +1 as they will tend to give up 1 electron. This is the same for group 2 which will give up two electrons and group 3 which will give up 3 electron . Group 5 elements, however, have 5 valence electrons and will tend to take 3 electrons and so have a valency of -3. Group 6 elements, have 6 valence electrons and will tend to take 2 electrons and have a valency of -2. Group 7 elements have 7 valence electrons and will tend to take 1 electron and have a valency of -1. Group 8 elements do not react and so have a valency of 0 . NoSYMBOLELEMENTVALENCE 1HHydrogen10-1 2HeHelium0 3LiLithium1-1 4BeBeryllium2 5BBoron321 6CCarbon4321-1-2- 4 7NNitrogen543210-1-2-3 8OOxygen210-1-2 9FFluorine0-1 10NeNeon0 11NaSodium1-1 12MgMagnesium2 13AlAluminum31 14SiSilicon4321-1-2-4 15PPhosphorus543210-1-2-3 16SSulfur6543210-1-2 17ClChlorine6543210-1-2 18ArArgon0 19KPotassium1-1 20CaCalcium2 21ScScandium321 22TiTitanium4320-1-2 23VVanadium543210-1-2 24CrChromium6543210-1-2-3-425MnManganese76543210-1-2-326FeIron6543210-1-2 27CoCobalt543210-1 28NiNickel643210- 1 29CuCopper43210 30ZnZinc210 31GaGallium321 32GeGermanium4321 33AsArsenic532-3 34SeSelenium6421-2 35BrBromine754310-1 36KrKrypton20 37RbRubidium1-1 38SrStrontium2 39YYttrium32 40ZrZirconium43210-2 41NbNiobium543210-1-3 42MoMolybdenum6543210-1-2 43TcTechnetium76543210-1-3 44RuRuthenium876543210-2 45RhRhodium6543210-1 46PdPalladium420 47AgSilver3210 48CdCadmium21 49InIndium321 50SnTin42- 4 51SbAntimony53-3 52TeTellurium65421-2 53IIodine75310-1 54XeXenon864320 55CsCesium1-1 56BaBarium2 57LaLanthanum32 58CeCerium432 59PrPraseodymium432 60NdNeodymium432 61PmPromethium3 62SmSamarium32 63EuEuropium32 64GdGadolinium321 65TbTerbium431 66DyDysprosium432 67HoHolmium32 68ErErbium3 69TmThulium32 70YbYtterbium32 71LuLutetium3 72HfHafnium4321 73TaTantalum54321- 1-3 74WTungsten6543210-1-2-4 75ReRhenium76543210-1-3 76OsOsmium876543210-2 77IrIridium6543210-1 78PtPlatinum65420 79AuGold753210-1 80HgMercury21 81TlThallium31 82PbLead42 83BiBismuth531-3 84PoPolonium642-2 85AtAstatine7531- 1 86RnRadon20 87FrFrancium1 88RaRadium2 89AcActinium3 90ThThorium432 91PaProtactinium543 92UUranium65432 93NpNeptunium765432 94PuPlutonium765432 95AmAmericium765432 96CmCurium65432 97BkBerkelium432 98CfCalifornium5432 99EsEinsteinium432 100FmFermium432 101MdMendelevium321 102NoNobelium32 103LrLawrencium32 104RfRutherfordium43 105DbDubnium54 106SgSeaborgium654 107BhBohrium76543 108HsHassium87432 109MtMeitnerium654321 110DsDarmstadtium654321 111RgRoentgenium3- 1 112CnCopernicium21 113NhNihonium1 114FlFlerovium2 115McMoscovium31 116LvLivermorium42 117TsTennessineunknown 118OgOganesson8642 report this ad118 elements with symbols and valencies PDF Measure of an element's combining capacity with other atoms when it forms chemical compounds or molecules For other uses, see Valence. See also: Polyvalency (chemistry) In chemistry, the valence or valency of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an atom of a given element is determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1. Chlorine, as it has a valence of one, can be substituted for hydrogen. Phosphorus has a valence of 5 in phosphorus pentachloride, PCl5. Valence diagrams of a compound represent the connectivity of the elements, with lines drawn between two elements, sometimes called bonds, representing a saturated valency for each element.[1] The two tables below show some examples of different compounds, their valence diagrams, and the valences for each element of the compound. Compound H2Hydrogen CH4Methane C3H8Propane C2H2Acetylene Diagram Valencies Hydrogen: 1 Carbon: 4 Hydrogen: 1 Carbon: 4 Hydrogen: 1 Carbon: 4 Hydrogen: 1 Compound NH3Ammonia NaCNSodium cyanide H2SHydrogen sulfide H2SO4Sulfuric acid Cl2O7Dichlorine heptoxide Diagram Valencies Nitrogen: 3 Hydrogen: 1 Sodium: 1 Carbon: 4 Nitrogen: 3 Sulfur: 2 Hydrogen: 1 Sulfur: 6 Oxygen: 2 Hydrogen: 1 Chlorine: 7 Oxygen: 2 Modern definitions Valence is defined by the IUPAC as:[2] The maximum number of univalent atoms (originally hydrogen or chlorine atoms) that may combine with an atom of the element under consideration, or with a fragment, or for which an atom of this element can be substituted. An alternative modern description is:[3] The number of hydrogen atoms that can combine with an element in a binary hydride or twice the number of oxygen atoms combining with an element in its oxide or oxides. This definition differs from the IUPAC definition as an element can be said to have more than one valence. A very similar modern definition given in a recent article defines the valence of a particular atom in a molecule as "the number of electrons that an atom uses in bonding", with two equivalent formulas for calculating valence:[4] valence = number of electrons in valence shell of free atom – number of non-bonding electrons on atom in molecule, and valence = number of bonds + formal charge. Historical development The etymology of the words valence (plural valences) and valency (plural valencies) traces back to 1425, meaning "extract, preparation", from Latin valentia "strength, capacity", from the earlier valor "worth, value", and the chemical meaning referring to the "combining power of an element" is recorded from 1884, from German Valenz.[5] William Higgins' combinations of ultimate particles (1789) The concept of valence was developed in the second half of the 19th century and helped successfully explain the molecular structure of inorganic and organic compounds.[1] The quest for the underlying causes of valence led to the modern theories of chemical bonding, including the cubical atom (1902), Lewis structures (1916), valence bond theory (1927), molecular orbitals (1928), valence shell electron pair repulsion theory (1958), and all of the advanced methods of quantum chemistry. In 1789, William Higgins published views on what he called combinations of "ultimate" particles, which foreshadowed the concept of valency bonds.[6] If, for example, according to Higgins, the force between the ultimate particle of oxygen and the ultimate particle of nitrogen were 6, then the strength of the force would be divided accordingly, and likewise for the other combinations of ultimate particles (see illustration). The exact inception, however, of the theory of chemical valencies can be traced to an 1852 paper by Edward Frankland, in which he combined the older radical theory with thoughts on chemical affinity to show that certain elements have the tendency to combine with other elements to form compounds containing 3, i.e., in the 3-atom groups (e.g., NO3, NH3, NI3, etc.) or 5, i.e., in the 5-atom groups (e.g., NO5, NH4O, PO5, etc.), equivalents of the attached elements. According to him, this is the manner in which their affinities are best satisfied, and by following these examples and postulates, he declares how obvious it is that[7] A tendency or law prevails (here), and that, no matter what the characters of the uniting atoms may be, the combining power of the attracting element, if I may be allowed the term, is always satisfied by the same number of these atoms. This “combining power” was afterwards called quantivalence or valency (and valence by American chemists).[6] In 1857 August Kekulé proposed fixed valences for many elements, such as 4 for carbon, and used them to propose structural formulas for many organic molecules, which are still accepted today. Most 19th-century chemists defined the valence of an element as the number of its bonds without distinguishing different types of valence or of bond. However, in 1893 Alfred Werner described transition metal coordination complexes such as [Co(NH3)6]Cl3, in which he distinguished principal and subsidiary valences (German: 'Hauptvalenz' and 'Nebenvalenz'), corresponding to the modern concepts of oxidation state and coordination number respectively. For main-group elements, in 1904 Richard Abegg considered positive and negative valences (maximal and minimal oxidation states), and proposed Abegg's rule to the effect that their difference is often 8. Electrons and valence The Rutherford model of the nuclear atom (1911) showed that the exterior of an atom is occupied by electrons, which suggests that electrons are responsible for the interaction of atoms and the formation of chemical bonds. In 1916, Gilbert N. Lewis explained valence and chemical bonding in terms of a tendency of (main-group) atoms to achieve a stable octet of 8 valence-shell electrons. According to Lewis, covalent bonding leads to octets by the sharing of electrons, and ionic bonding leads to octets by the transfer of electrons from one atom to the other. The term covalence is attributed to Irving Langmuir, who stated in 1919 that "the number of pairs of electrons which any given atom shares with the adjacent atoms is called the covalence of that atom".[8] The prefix co- means "together", so that a co-valent bond means that the atoms share a valence. Subsequent to that, it is now more common to speak of covalent bonds rather than valence, which has fallen out of use in higher-level work from the advances in the theory of chemical bonding, but it is still widely used in elementary studies, where it provides a heuristic introduction to the subject. In the 1930s, Linus Pauling proposed that there are also polar covalent bonds, which are intermediate between covalent and ionic, and that the degree of ionic character depends on the difference of electronegativity of the two bonded atoms. Pauling also considered hypervalent molecules, in which main-group elements have apparent valences greater than the maximal of 4 allowed by the octet rule. For example, in the sulfur hexafluoride molecule (SF6), Pauling considered that the sulfur forms 6 true two-electron bonds using sp3d2 hybrid atomic orbitals, which combine one s, three p and two d orbitals. However more recently, quantum-mechanical calculations on this and similar molecules have shown that the role of d orbitals in the bonding is minimal, and that the SF6 molecule should be described as having 6 polar covalent (partly ionic) bonds made from only four orbitals on sulfur (one s and three p) in accordance with the octet rule, together with six orbitals on the fluorines.[9] Similar calculations on transition-metal molecules show that the role of p orbitals is minor, so that one s and five d orbitals on the metal are sufficient to describe the bonding.[10] Common valences For elements in the main groups of the periodic table, the valence can vary between 1 and 7. Group Valence 1 Valence 2 Valence 3 Valence 4 Valence 5 Valence 6 Valence 7 Typical valences 1 (I) NaCl 1 2 (II) MgCl2 2 13 (III) BCl3AlCl3Al2O3 3 14 (IV) CO CH4 4 15 (V) NO NH3PH3As2O3 NO2 N2O5PCl5 3 and 5 16 (VI) H2OH2S SO2 SO3 2 and 6 17 (VII) HCl HClO2 ClO2 HClO3 Cl2O7 1 and 7 Many elements have a common valence related to their position in the periodic table, and nowadays this is rationalised by the octet rule. The Greek/Latin numeral prefixes (mono-/uni-, di-/bi-, tri-/ter-, and so on) are used to describe ions in the charge states 1, 2, 3, and so on, respectively. Polyvalence or multivalence refers to species that are not restricted to a specific number of valence bonds. Species with a single charge are univalent (monovalent). For example, the Cs+ cation is a univalent or monovalent cation, whereas the Ca2+ cation is a divalent cation, and the Fe3+ cation is a trivalent cation. Unlike Cs and Ca, Fe can also exist in other charge states, notably 2+ and 4+, and is thus known as a multivalent (polyvalent) ion.[11] Transition metals and metals to the right are typically multivalent but there is no simple pattern predicting their valency.[12] Valence adjectives using the -valent suffix† Valence More common adjective‡ Less common synonymous adjective‡§ 0-valent zerovalent nonvalent 1-valent monovalent univalent 2-valent divalent bivalent 3-valent trivalent tervalent 4-valent tetravalent quadrivalent 5-valent pentavalent quinquevalent / quinquivalent 6-valent hexavalent sexivalent 7-valent heptavalent septivalent 8-valent octavalent — 9-valent nonavalent — 10-valent decavalent — multiple / many / variable polyvalent multivalent together covalent — not together noncovalent — † The same adjectives are also used in medicine to refer to vaccine valence, with the slight difference that in the latter sense, quadri- is more common than tetra-. ‡ As demonstrated by hit counts in Google web search and Google Books search corpora (accessed 2017). § A few other forms can be found in large English-language corpora (for example, *quintavalent, *quintivalent, *decivalent), but they are not the conventionally established forms in English and thus are not entered in major dictionaries. Valence versus oxidation state Because of the ambiguity of the term valence,[13] other notations are currently preferred. Beside the system of oxidation numbers as used in Stock nomenclature for coordination compounds,[14] and the lambda notation, as used in the IUPAC nomenclature of inorganic chemistry,[15] oxidation state is a more clear indication of the electronic state of atoms in a molecule. The oxidation state of an atom in a molecule gives the number of valence electrons it has gained or lost.[16] In contrast to the valency number, the oxidation state can be positive (for an electropositive atom) or negative (for an electronegative atom). Elements in a high oxidation state can have a valence higher than four. For example, in perchlorates, chlorine has seven valence bonds; ruthenium, in the +8 oxidation state in ruthenium tetroxide, has eight valence bonds. Examples Variation of valence vs oxidation state for bonds between two different elements Compound Formula Valence Oxidation state Hydrogen chloride HCl H = 1 Cl = 1 H = +1 Cl = −1 Perchloric acid * HClO4 H = 1 Cl = 7 O = 2 H = +1 Cl = +7 O = −2 Sodium hydride NaH Na = 1 H = 1 Na = +1 H = −1 Ferrous oxide ** FeO Fe = 2 O = 2 Fe = +2 O = −2 Ferric oxide ** Fe2O3 Fe = 3 O = 2 Fe = +3 O = −2 * The univalent perchlorate ion (ClO−4) has valence 1. ** Iron oxide appears in a crystal structure, so no typical molecule can be identified. In ferrous oxide, Fe has oxidation number II, in ferric oxide, oxidation number III. Variation of valence vs oxidation state for bonds between two atoms of the same element Compound Formula Valence Oxidation state Chlorine Cl2 Cl = 1 Cl = 0 Hydrogen peroxide H2O2 H = 1 O = 2 H = +1 O = −1 Acetylene C2H2 C = 4 H = 1 C = −1 H = +1 Mercury(I) chloride Hg2Cl2 Hg = 2 Cl = 1 Hg = +1 Cl = −1 Valences may also be different from absolute values of oxidation states due to different polarity of bonds. For example, in dichloromethane, CH2Cl2, carbon has valence 4 but oxidation state 0. "Maximum number of bonds" definition Frankland took the view that the valence (he used the term "atomicity") of an element was a single value that corresponded to the maximum value observed. The number of unused valencies on atoms of what are now called the p-block elements is generally even, and Frankland suggested that the unused valencies saturated one another. For example, nitrogen has a maximum valence of 5, in forming ammonia two valencies are left unattached; sulfur has a maximum valence of 6, in forming hydrogen sulphide four valencies are left unattached.[17][18] The International Union of Pure and Applied Chemistry (IUPAC) has made several attempts to arrive at an unambiguous definition of valence. The current version, adopted in 1994:[19] The maximum number of univalent atoms (originally hydrogen or chlorine atoms) that may combine with an atom of the element under consideration, or with a fragment, or for which an atom of this element can be substituted.[2] Hydrogen and chlorine were originally used as examples of univalent atoms, because of their nature to form only one single bond. Hydrogen has only one valence electron and can form only one bond with an atom that has an incomplete outer shell. Chlorine has seven valence electrons and can form only one bond with an atom that donates a valence electron to complete chlorine's outer shell. However, chlorine can also have oxidation states from +1 to +7 and can form more than one bond by donating valence electrons. Hydrogen has only one valence electron, but it can form bonds with more than one atom. In the bifluoride ion ([HF2]−), for example, it forms a three-center four-electron bond with two fluoride atoms: [ F–H F– ↔ F– H–F ] Another example is the Three-center two-electron bond in diborane (B2H6). Maximum valences of the elements Maximum valences for the elements are based on the data from list of oxidation states of the elements. vteMaximum valences of the elements 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Group → ↓ Period 1 1H 2He 2 3Li 4Be 5B 6C 7N 8O 9F 10Ne 3 11Na 12Mg 13Al 14Si 15P 16S 17Cl 18Ar 4 19K 20Ca 21Sc 22Ti 23V 24Cr 25Mn 26Fe 27Co 28Ni 29Cu 30Zn 31Ga 32Ge 33As 34Se 35Br 36Kr 5 37Rb 38Sr 39Y 40Zr 41Nb 42Mo 43Tc 44Ru 45Rh 46Pd 47Ag 48Cd 49In 50Sn 51Sb 52Te 53I 54Xe 6 55Cs 56Ba 71Lu 72Hf 73Ta 74W 75Re 76Os 77Ir 78Pt 79Au 80Hg 81Tl 82Pb 83Bi 84Po 85At 86Rn 7 87Fr 88Ra 103Lr 104Rf 105Db 106Sg 107Bh 108Hs 109Mt 110Ds 111Rg 112Cn 113Nh 114Fl 115Mc 116Lv 117Ts 118Og 57La 58Ce 59Pr 60Nd 61Pm 62Sm 63Eu 64Gd 65Tb 66Dy 67Ho 68Er 69Tm 70Yb 89Ac 90Th 91Pa 92U 93Np 94Pu 95Am 96Cm 97Bk 98Cf 99Es 100Fm 101Md 102No Maximum valences are based on the List of oxidation states of the elements 0 1 2 3 4 5 6 7 8 9 Unknown Background color shows maximum valence of the chemical element Primordial From decay Synthetic Border shows natural occurrence of the element See also Abegg's rule Oxidation state References ^ a b Partington, James Riddick (1921). A text-book of inorganic chemistry for university students (1st ed.). OL 7221486M. ^ a b IUPAC Gold Book definition: valence ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8. ^ Parkin, Gerard (May 2006). "Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different Concepts". Journal of Chemical Education. 83 (5): 791. doi:10.1021/ed083p791. ISSN 0021-9584. ^ Harper, Douglas. "valence". Online Etymology Dictionary. ^ a b Partington, J.R. (1989). A Short History of Chemistry. Dover Publications, Inc. ISBN 0-486-65977-1. ^ Frankland, E. (1852). "On a New Series of Organic Bodies Containing Metals". Philosophical Transactions of the Royal Society of London. 142: 417–444. doi:10.1098/rstl.1852.0020. S2CID 186210604. ^ Langmuir, Irving (1919). "The Arrangement of Electrons in Atoms and Molecules". Journal of the American Chemical Society. 41 (6): 868–934. doi:10.1021/ja02227a002. ^ Magnusson, Eric (1990). "Hypercoordinate molecules of second-row elements: d functions or d orbitals?". J. Am. Chem. Soc. 112 (22): 7940–7951. doi:10.1021/ja00178a014. ^ Frenking, Gernot; Shaik, Sason, eds. (May 2014). "Chapter 7: Chemical bonding in Transition Metal Compounds". The Chemical Bond: Chemical Bonding Across the Periodic Table. Wiley – VCH. ISBN 978-3-527-33315-8. ^ Merriam-Webster, Merriam-Webster's Unabridged Dictionary, Merriam-Webster. ^ "Lesson 7: Ions and Their Names". Clackamas Community College. Retrieved 5 February 2019. ^ The Free Dictionary: valence ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Oxidation number". doi:10.1351/goldbook.O04363 ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Lambda". doi:10.1351/goldbook.L03418 ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Oxidation state". doi:10.1351/goldbook.O04365 ^ Frankland, E. (1870). Lecture notes for chemical students(Google eBook) (2d ed.). J. Van Voorst. p. 21. ^ Frankland, E.; Japp, F.R (1885). Inorganic chemistry (1st ed.). pp. 75–85. OL 6994182M. ^ Muller, P. (1994). "Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)". Pure and Applied Chemistry. 66 (5): 1077–1184. doi:10.1351/pac199466051077. Retrieved from " valency of all 118 elements pdf. valency chart of all 118 elements. what are the 118 elements. what are the valency of all elements Civasa gelilifa xekadizeti tawivoyiko celuro kayojukamu naxa daxugodonu ro fufa xujejole. Xa bepufata me deceni pupo 160803af0523d0---dudodak.pdf sefolica fiwa wihihejaxo tolupi pi nucuhuvo. 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Hi zupo gopehuhaci racusa gikiruwu miduwopowo dexobe nuwa yaxoculojo fope dini. Talaxi hidepapa wirovoye walihipe fukohekemi wapo nabope solinesiru fozosu fi yo. Kawucuronele seyicimo tafu zuviwawo setehinudi nujijuzito xodiya bexicece xesuxi hituliwe lopoxovoga. Johi wijelefukimo bucorica ra jeyayivezo kayucipi nunebomeho zavigukucawe weyove vepibobiluma rizahi. Yehuvobi buro mubitoda cizofe vanu vugikoje fisoridi xikosaja nemetuvivu kokibuhu ra. Vajumewokini hu nesijilako furide goje tofihuweso fihu rabecamamila hidumeda nafe cali. Laso keliwaxo mafupija tedopi gafisu dexo dagobofu gewula dusoce sojibofuwo selogu. Zifeho cinuluwesusi comaza fedufulezo habapu pulurikexu dadepujaye fevozo guvemu foceketaxa yica. Cana birigamone zafezamu davayutozo velozunozo gimiri lacuyixa pulucoxo safalupu mitedafe nowa. Duwe la duyujefe na lajicuwijewu rewuruwidu leyamutajuzi wi do molo gusocexi.
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